Crystal structure of 5-(4-benzyloxyphenyl)-3-(4-methoxyphenyl)-6-methylcyclohex-2-en-1-one
نویسندگان
چکیده
The title compound, C27H26O3, crystallized with two independent mol-ecules (A and B) in the asymmetric unit. In mol-ecule A, the plane of the central benzene ring forms dihedral angles of 75.78 (14) and 52.75 (16)° with that of the terminal benzene rings, and the dihedral angle between the planes of the terminal benzene rings is 51.49 (17)°. The corresponding values for mol-ecule B are 75.18 (14), 58.11 (16) and 47.91 (16)°, respectively. The cyclo-hexene ring adopts an envelope conformation in both mol-ecules, with the C atom to which is attached the central benzene ring as the flap. The crystal packing, is stabilized by C-H⋯π inter-actions.
منابع مشابه
Crystal structure of 1-{3-acetyl-2-(4-chlorophenyl)-6-hydroxy-4-[(2-hydroxypropyl)amino]-6-methylcyclohex-3-en-1-yl}ethanone
In the title compound, C20H26ClNO4, the central cyclo-hexene ring adopts an approximate envelope conformation with the C atom binding with the hy-droxy group at the tip of the flap. There is an intramolecular N-H⋯O hydrogen bond generating an S(6) ring motif. In the crystal, classical O-H⋯O hydrogen bonds and weak C-H⋯O and C-H⋯Cl inter-actions link the mol-ecules, forming a three-dimensional s...
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عنوان ژورنال:
دوره 71 شماره
صفحات -
تاریخ انتشار 2015